I would bury a bunch of gold coins and act like it's my last one from the family heirlooms anytime I spent one. Shaving off chunks of a gold bar makes it pretty obvious there's more at the source. But yeah, ammo will be the new currency.
Definitely, "usable thing" such as ammo will be the currency.
After all, if it is societal collapse, that means no society, hence no bartering for shiny bits of metal. Why would anyone care about gold, or silver? There's no merchants. No social cohesion. What will you do with the gold? Look at it? Hope someone will trade stored food for it?
Why would anyone?
The unfortunate part is that it is far harder to move or carry or hide your wealth. It's quite tangible. Where do you store a million rounds of ammo, or maybe water filters, or even MREs or canned food? It all takes space, and in the end?
No person will horde such wealth if anyone knows they have it. It will be taken.
That's why prepping really only makes sense for temporary disasters in your region.